Preparation and properties of Polyurethane coating based on Modified castor oil, Commercial acrylate polyols and polysiloxane
Keywords:
Polyurethane, castor oil, Acrylated polyols, Diisocyanate, Polysilazane, MS steel panel, Drying time, mechanical properties chemical resistance
Abstract
The polyurethanes (PUs) were prepared by polycondensation of modified castor oil (MCO)[Castor oil-succinic anhydride-penaerythritol reaction product], commercial acrylate polyols (AP) and Isophorone diisocyanate (IPDC) at various properties. The resultant PUs were then treated with monocarbinol terminated polydimethyl siloxane (MTPS) to neutralize –NCO groups. The resultant PU coatings were applied on MS steel panels at room temperature. All the PU coatings were characterized by physical, chemical and mechanical properties.
References
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23. Allauddin, S, Narayan, R, Raju, KVSN, ‘‘Synthesis and Properties of Siloxane- Crosslinked Polyurethane urea/Silica Hybrid Films from Castor Oil.’’ J. Coat. Technol. Res., 11 (3), 397–407 (2014).
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25. Akram, D, Sharmin, E, Ahmad, S, ‘‘Linseed Polyurethane/ Tetraethoxy ortho silane /Fumed Silica Hybrid Nanocomposite Coatings: Physico-Mechanical and Potentiodynamic Polarization Measurements Studies.’’ Prog. Org. Coat., 77 (5) 957–964 (2014).
26. Krishnamurthy, VN, Thomas, S, ‘‘ISRO Polyol—The Versatile Binder for Composite Solid Propellants for Launch Vehicles and Missiles.’’ Def. Sci. J., 37 (1) 29–37 (1987).
2. Shirkel, A, Bharatkumar, D, Ketan, K, ‘‘Novel Applications of Castor Oil Based Polyurethanes: A Short Review.’’ Polym. Sci. Ser. B., 57 (4) 292–297 (2015).
3. Dhiraj K.Kaikade and Anahja S. Sabnis,Polyurethane foams from vegetable oil based Polyols: A review, Polymer Bulletin,80,2239-2261(2023).
4. Poonam Singh,Anuj Rana,Niranjan Karak,Indresh Kumar,Srarendra Rana and Pankaj Kumar,Sustainable smart anti-corrosion coating materials derived from vegetable oil derivatives: A review,RSC Adv.,13,3910-3941(2023).
5. Payan M. Paraskar,Mayur S,Prabhudesai, Vinod M. Hatakar, Ravindra D,Kulkarni, Vegetables oil based Polyurathane coating a sustainable approach: A review,Progress in Organic coatings,156,106287 (2021).
6. Achaya, KT, ‘‘Chemical Derivatives of Castor Oil.’’ J. Am. Oil Chem. Soc., 48 (11), 758–763 (1971).
7. Allauddin Shaik,Kabir Baidya, Kirankumar Nehete, Sabarna Shyamroy, Synthesis,Characterization of Castor oil based branched Polyols from renewable resources and their Poleurethane-urea coating,J,Coat, Technol. Res.,16,387-400(2019).
8. Thakur, S, Barua, S, Karak, N, ‘‘Self-Healable Castor Oil Based Tough Smart Hyperbranched Polyurethane Nanocomposite with Antimicrobial Attributes.’’ RSC Adv., 5 2167–2176 (2015).
9. Karak, N, Rana, S, Cho, JW, ‘‘Synthesis and Characterization of Castor-Oil-Modified Hyperbranched Polyurethanes.’’ J. Appl. Polym. Sci, 112 (2) 736–743 (2009).
10. Thakur, S, Karak, N, ‘‘Castor Oil-Based Hyperbranched Polyurethanes as Advanced Surface Coating Materials.’’ Prog. Org. Coat., 76 (1) 157–164 (2013).
11. Das, B, Konwar, U, Mandal, M, Karak, N, ‘‘Sunflower Oil Based Biodegradable Hyperbranched Polyurethane as a Thin Film Material.’’ Ind. Crops Prod., 44 396–404 (2013).
12. Moghadam, PN, Yarmohamadi, M, Hasanzadeh, R, Nuri, S, ‘‘Preparation of Polyurethane Wood Adhesives by Polyols Formulated with Polyester Polyols Based on Castor Oil.’’ Int. J. Adhes. Adhes., 68 273–282 (2016).
13. Meer, KMS, Sankar, RM, Paul, J, Jaisankara, SN, Mandal, AB, ‘‘The Influence of Applied Silica Nanoparticles on a Bio-Renewable Castor Oil Based Polyurethane Nanocomposite and Its Physicochemical Properties.’’ Phys. Chem. Chem. Phys, 16 9276–9288 (2014).
14. Ahmad, S, Zafar, F, Sharmin, E, Garg, N, Kashif, M, ‘‘Synthesis and Characterization of Corrosion Protective Polyurethanefattyamide/Silica Hybrid Coating Material.’’ Prog. Org. Coat, 73 (1) 112–117 (2012) 26. Williams, GI, Wool, RP, ‘‘Composites from Natural Fibers and Soy Oil Resins.’’ Appl. Compos. Mater., 7 421–432 (2000).
15. Lligadas, G, Ronda, JC, Marina, G, Cadiz, V, ‘‘Bionanocomposites from Renewable Resources: Epoxidized Linseed Oil, Polyhedral Oligomeric Silsesquioxanes Hybrid Materials.’’ Biomacromolecules, 7 (12) 3521–3526 (2006).
16. Hiroshi, U, Mai, K, Takashi, T, Mitsuru, N, Arimitsu, U, Shiro, K, ‘‘Green Nanocomposites from Renewable Resources: Plant Oil, Clay Hybrid Materials.’’ Chem. Mater., 15 (13) 2492–2494 (2003).
17. Siyanbola, TO, Sasidhar, K, Anjaneyulu, B, Kumar, KP, Rao, BVSK, Ramanuj, N, Olaofe, O, Akintayo, ET, Raju, KVSN, ‘‘Anti-Microbial and Anti-Corrosive Poly (ester amide urethane) Siloxane Modified ZnO Hybrid Coatings from Thevetia Peruviana Seed Oil.’’ J. Mater. Sci, 48 (23), 8215–8227 (2013).
18. Lligadas, G, Callau, L, Ronda, JC, Galia, M, Cadiz, V, ‘‘Novel Organic–Inorganic Hybrid materials from Renewable Resources: Hydrosilylation of Fatty Acid Derivatives.’’ J. Poly. Sci. Part A: Poly. Chem., 43 (24) 6295–6307 (2005).
19. M.Zhou,Z.Ha,L.Lei,Y.Xia,P.Mao,X.Chen,B.Fan,S.Shi,Caster oil based transparent and omniphobic polyurethane coatings with hardnen, anti smudge and anti corrosive properties,Progress in Organic coating,172,107120 (2022).ACS App. Mater. Interfaces,15(5),7427-7447(2023).
20. Lligadas, G, Ronda, JC, Marina, G, Cadiz, V, ‘‘Novel Silicon-Containing Polyurethanes from Vegetable Oils as Renewable Resources. Synthesis and Properties.’’ Biomacromolecules, 7(8) 2420–2426 (2006).
21. Kamal, MSM, Rajavelu, MS, Sellamuthu, NJ, Asit, BM, ‘‘Physicochemical Studies on Polyurethane/Siloxane Cross-Linked Films for Hydrophobic Surfaces by the Sol- Gel Process.’’ J. Phys. Chem. B, 117 (9) 2682–2694 (2013).
22. Ivan, SR, Jaroslava, B, Ivan, K, Helena, V, Radmila, R, Suzana, C, Nada, N, ‘‘The Properties of Polyurethane Hybrid Materials Based on Castor Oil.’’ Mater. Chem. Phys., 132 (1), 74–81 (2012).
23. Allauddin, S, Narayan, R, Raju, KVSN, ‘‘Synthesis and Properties of Siloxane- Crosslinked Polyurethane urea/Silica Hybrid Films from Castor Oil.’’ J. Coat. Technol. Res., 11 (3), 397–407 (2014).
24. Cumurcu, AA, Erciyes, T, ‘‘Synthesis and Properties of Alkoxysilane-Functionalized Urethane Oil/Titania Hybrid Films.’’ Prog. Org. Coat., 67 (3) 317–323 (2010).
25. Akram, D, Sharmin, E, Ahmad, S, ‘‘Linseed Polyurethane/ Tetraethoxy ortho silane /Fumed Silica Hybrid Nanocomposite Coatings: Physico-Mechanical and Potentiodynamic Polarization Measurements Studies.’’ Prog. Org. Coat., 77 (5) 957–964 (2014).
26. Krishnamurthy, VN, Thomas, S, ‘‘ISRO Polyol—The Versatile Binder for Composite Solid Propellants for Launch Vehicles and Missiles.’’ Def. Sci. J., 37 (1) 29–37 (1987).
Published
2023-08-07
How to Cite
Vimal D. Doshi, & Priyanka Jhalora. (2023). Preparation and properties of Polyurethane coating based on Modified castor oil, Commercial acrylate polyols and polysiloxane. Revista Electronica De Veterinaria, 24(2), 614-619. https://doi.org/10.69980/redvet.v24i2.2128
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